Greenhouse film additive masterbatch
Additive masterbatch for greenhouse films
Greenhouse movies
Chemists invest in the research and development of new additives to improve the performance of agricultural films. Since greenhouse films are a means of growing crops by overcoming adverse weather conditions, they are many fans of agriculture. Greenhouse films use sunlight radiation to bet internal microclimate parameters and also by using additives in plastic films with the aim of optimizing crop production.
Multi-layered degradable films are considered for covering and for use in removing or covering a frame to achieve a greenhouse effect. Polyolefin film can be used by having a degradable component where degradation is activated by ultraviolet and thermal stimuli. Degradable polyamine film changes color by changing the selected layer according to the season and geographical location of the covered area.
In agriculture, crop protection films or mulches are widely used. In conventional methods, a thin plastic film is placed on cultivated soil that has already been seeded or seeded or transplanted at the same time as soil cultivation.
with common plastic coating techniques; It is possible to cultivate the soil and apply the plastic film at the same time with the existing machinery. Such a technique allows earlier germination of seeds and protects seedlings from late-season frosts, which do not inhibit the growth of seedlings in the early stages of germination. In addition, this film can be used in conventional greenhouse structures or as a mulch film.
It is difficult to control the amount of degradation because the edges of the film due to exposure to the sun; Especially along the buried edges of mulch films, they degrade at a slower rate than the central parts of the film. In normal degradable agricultural films, the amount of destruction depends on the following conditions:
. Conditions of exposure to sunlight
rainfall
. Geographical location
Therefore, there are needs in the industry for a degradable film with a fast degradation rate that is more reliable in different seasons and geographical locations based on the drive mechanism; is controlled
In the industry there is a film that may be used for several growing seasons because
No need to replace every season
It is less expensive
It is not time consuming
The multilayer film consists of at least one polyolefin polymer and at least one degradable additive. In fact, the multilayer film is a degradable polymer-additive polyolefin composite that results in an agricultural film capable of degrading in a semi-predictable manner. Films are usually degradable and thermally degradable, so they are environmentally degradable under most conditions. The degradation caused by it is controlled by the selection of polyamine resins, specific additives and the concentration of additives.
Degradation may be accelerated by heat or exposure to sunlight. In addition, the plastic product may be heated without being heated by sunlight and even under anaerobic conditions, as it is heated to a certain temperature that exists in some agricultural environments, such as composting and composting.
The multi-layer degradable film allows producers to place the film in one field at a time, whereby this film lasts for more than one season, or by degradating the selected layer according to the season and geographical area. change color
Characteristics of greenhouse films
The greenhouse film should be able to maintain at least 50% of the original tensile strength in the film after the desired lifetime.
Greenhouse film should refer to the areas that are most exposed to solar energy.
The lifespan of the greenhouse film depends on the type of polymer chosen.
In greenhouse film, the use of additives mostly depends on the processing conditions during production.
Greenhouse film is affected by environmental conditions and exposure to sunlight, and its effect is in the final use.
Evolution of irradiance in greenhouse films
Generation one
In the 1970s the typical UV stabilization for greenhouse films was a combination of organic nickel (Ni-quencher) with a UV-absorber.
Today, in some areas, these formulations are still being used. But Ni-Quencher systems have experienced a significant downturn because elemental nickel is dangerous to the environment, especially if it is not disposed of adequately.
second generation
In the early 1980s, HALS-stabilizers (hydrogenated amine light stabilizers) came on the market. These stabilizers are often more effective in preventing polymer degradation due to heat and UV rays.
Generation Two Plus
Later, a combination of HALS grades was developed that improved chemical resistance. This system is transparent, and without the characteristic color of the film.
The third generation
Therefore, it was decided to create a new generation of HALS-Stabilizer, which is less sensitive to chemicals and performs better in harsh conditions. This stabilizer is often combined with inhibitors, which should neutralize the negative effect of chemicals as much as possible. This system is still sensitive to the elements, in situations where it is used as a powder.
The fourth generation
To disinfect greenhouses in 2000, a non-reciprocating light stabilization system with excellent light stabilization and thermal stabilization was introduced. This material generally has high chemical resistance.
The main application of this light stabilization system is mainly for the cultivation of ornamental plants and roses. Despite the higher cost of light stabilizer, the grower may save costs because this system increases the longevity of greenhouse films exposed to heavy pesticide use. This system offers the best possible resistance to higher levels of the chemical group and is also applicable depending on the area, making exposure possible with an excellent life time of less than 3 years.
Currently, the latest development is an economical alternative to the 4th generation NOR HALS Masterbatch, which has excellent resistance to agricultural chemicals and also enables a shelf life of less than 2 years, depending on the area and time of exposure to light. This system provides economic cost calculation in greenhouse film, this system is called 3rd Generation Plus. And it is transparent without having a characteristic color for the film.
Categories of GREENHOUSE FILM In a greenhouse film, a light stabilization system is rarely used. In most cases, functional additives are additionally used for optimal production of the product.
The first to fourth generation using ultraviolet rays of greenhouse films are used where there is little saving in heat inputs and where condensation is not a problem.
The ability of the greenhouse film to reflect during the nighttime infrared radiation in the greenhouse directly saves energy and keeps the thermal energy inside. Using IR-Barrier agent additives and anti-explosion additives, from 1/3 to 3R control of the generator / anti-biography / thermal material has thermal properties to control water condensation on the film. If installed correctly, the water will condense evenly on the film and become a film of water. This improves light transmission and reduces the risk of water splashing on the plants. Best for crops that respond to high direct light and warm temperatures.
ANTIFOG
Basics of Antifog The term fog is used to describe the condensation of water vapor on the surface of a transparent plastic film in the form of small and large droplets. The reason why we see water in the form of condensation droplets on the surface of the plastic film is the difference between the surface tension of water and the surface tension of the polymer, in addition to humidity and temperature difference.
What is an antifungal masterbatch?
Antifungal additive: It is included in the polymer matrix during the extrusion process. After extrusion, the additives migrate to the surface of the polymer, to the extent that the additives increase the elasticity of the polymer surface. A small amount of antifungal masterbatch dissolves in water droplets and reduces the surface tension of water.
Results of using additives
Additives used in greenhouse films cause light transmission in greenhouse films and its results are: higher plant growth rate – higher crop performance per plant – early maturity of the crop – reduces plant burning and plant drop.
Greenhouse films in crops
Greenhouse film with one-way migration into the outer layer of the film uses crystalline LDPE without antifungal additives. It acts as a protective barrier layer and represents about 25% of the total film thickness. The core layer effectively acts as a long-term reservoir for the film because the anti-inhibition additive is more compatible with the amorphous polymer. As the antifungal masterbatch is consumed inward, the core layer slowly releases the replacement additive only through one-way inward migration.
Base polymers of choice without the use of slip additives Regardless of mono or COEX film, the use of any migration slip additive can completely nullify the Masterbatch Antifog effect. Because there are inconsistent functional effects on the film surface. Additives are able to absorb certain amounts of antifog active substance on the surface of their particles. If such additives are used, the dosage of Antifog MB should be adjusted to compensate for the absorption effect. In COEX films, the antifog effect is significantly influenced by the choice of polymers in the respective layers.
Since the anti-dew masterbatch effect depends to a large extent on the conditions of final agricultural use in and around the greenhouse, so it should be tested under practical conditions before taking the anti-greenhouse formula on a commercial scale.
Long-wavelength infrared energy radiation can pass through the greenhouse. At night, warm plants, soil and components inside the greenhouse lose their high energy by transmitting long wave radiation (infrared) to the cold sky. The amount of this loss depends not only on the temperature of the plants and the atmospheric conditions of clouds, carbon dioxide and , but it also depends on the properties of the greenhouse film covering material.
The composition of the film, the choice of polymer and the use of suitable additives significantly affect this property, and by using suitable additives to keep the greenhouse warm at night in the cold seasons of the year, it ensures that early crops in the spring And the lengthening of the product is used in the fall.
Choosing the correct polymers for the film or using special additives such as IR barriers will also affect the thickness of the film.
Thinner films tend to be warmer at night and winter temperatures. When using IR-Barrier additives, the greenhouse film’s ability to reflect long-wavelength infrared radiation into the greenhouse directly saves energy and retains thermal energy.
There are two main methods of imparting IR Barrier properties to LDPE greenhouse films
1. The use of inorganic IR Barrier additives in LDPE films is especially applied to mono films, and the thinner the film, the higher the addition rate is required.
2. The use of EVA ethylene vinyl acetate copolymer, which is often applied in COEX films, because EVA has special IR barrier properties in terms of VA properties and film thickness.
Light dispersion addtive masterbatch
Using the light distributor masterbatch
LED lamp is a light emitting diode that can be used for lighting, low energy consumption, high brightness, but the light radiation is strong and does not allow the person to be unable to open, or unable to get soft visual effects. We introduce the light diffuser product. we pay
1) The light emission agent used in different shades can resolve the point source to the surface light, the light is soft and the brightness is high enough.
2) The light scattering agents must be in the LED TV backlight module, the TV can achieve low energy consumption, low heat, long life, and the color is more vivid.
3) The light diffusing material can be used in the industry of LED epoxy packaging, light and other bright colors.
Light distributor masterbatch feature
- Higher temperature
- Resistance to aging and heat
- Resistance to solvents
- Being non-melting
- Resistance to organic substances and resistance to acid
- High mechanical resistance to beats
- It does not change the color.
- Light transmission can reach more than 86%.
- Compared to other similar light emitting materials, they have higher brightness and less additives.
- Uniform particle size distribution
- It can effectively make the point of light scattering uniform.
- It can change bright incident light to soft light.
- Low light loss and high light scattering efficiency
- The strength of optical plastic plate improved the diffusion membrane with flame ignition resistance and smoke suppression effect
- Light and homogeneous